Skip to main content

Posts

Showing posts with the label d‑d Transitions

The Color of Coordination Complexes: A Quantitative Dive into Crystal Field Theory

The Color of Coordination Complexes | Crystal Field Theory | SM-EDUCATE Chemistry 🧪 SM-EDUCATE CHEMISTRY June 07, 2026 The Color of Coordination Complexes: A Quantitative Dive into Crystal Field Theory 🎨 d-orbital splitting · Spectrochemical series · λ = hc / Δ · Why emeralds are green 📤 SHARE Coordination Chemistry Crystal Field Theory d-d Transitions Spectrochemical Series Inorganic Chemistry Colour of Complexes Why is [Ti(H₂O)₆]³⁺ violet? Why is [Cu(H₂O)₆]²⁺ blue? And why does [Ni(NH₃)₆]²⁺ look completely different from [Ni(H₂O)₆]²⁺? The answer lies in Crystal Field Theory (CFT) — a beautiful, quantitative model that explains how ligands split the d‑orbitals of transition metals, and how electrons jumping between those split levels absorb specific colours of light. Octahedral Crystal Field Splitting (Δ oct ) High | ...