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Showing posts with the label Nucleophilic Substitution

SN1 vs SN2: How to Tell Which Mechanism You're Looking At

SN1 vs SN2: How to Tell Which Mechanism You're Looking At These four letters cause more confusion than almost anything else in organic chemistry — not because the mechanisms are hard individually, but because students never learn a reliable way to decide which one they're looking at under exam pressure. Here's a clean way to tell them apart, every time. The basics first SN1 = Substitution, Nucleophilic, Unimolecular (rate depends on only 1 species) SN2 = Substitution, Nucleophilic, Bimolecular (rate depends on 2 species) That's literally what the numbers mean — not "1 step" and "2 steps," which is the most common misconception. It's about how many molecules are involved in the rate-determining step. SN2: the one-step story SN2 happens in a single, smooth motion — the nucleophile attacks from the opposite side of the leaving group at the exact same time the leaving group departs. No intermediate forms. Rate = k[substrate][nucleo...