11 · Organic Chemistry
11.1 Alkanes and Alkenes
The two main homologous series at IGCSE level: alkanes (CnH2n+2, saturated, single bonds only) and alkenes (CnH2n, unsaturated, contain a C=C double bond).
Alkenes can be tested using bromine water: alkenes decolourise bromine water (orange → colourless) due to the double bond; alkanes do not.
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11.2 Key Reactions and Polymers
Combustion (complete): alkane + oxygen → carbon dioxide + water. Addition reactions of alkenes: react with hydrogen (nickel catalyst) to form alkanes; with steam to form alcohols; with bromine to form dibromo compounds.
Fermentation: glucose → ethanol + carbon dioxide, using yeast, anaerobically. Polymers: large molecules made of repeating monomers. Addition polymerization joins monomers with a C=C double bond with no other product formed (e.g. ethene → poly(ethene)).
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