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CS-991 · Module O-X4
Nomenclature Basics
Class X · Organic Chemistry
▶ Introduction to IUPAC Nomenclature
▶ IUPAC Naming Rules with Examples
▶ Practice Naming Organic Compounds
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✍️ IUPAC Naming: The Basics
Every IUPAC name has three parts: Prefix (substituents) + Parent chain (carbon count) + Suffix (functional group).
- Find the longest continuous carbon chain containing the main functional group.
- Number the chain to give the lowest possible locants to the functional group and substituents.
- Name substituents alphabetically with their position numbers.
📊 Carbon Chain Prefixes
| Carbons | Prefix | Carbons | Prefix |
|---|---|---|---|
| 1 | Meth- | 5 | Pent- |
| 2 | Eth- | 6 | Hex- |
| 3 | Prop- | 7 | Hept- |
| 4 | But- | 8 | Oct- |
📊 Common Suffixes
| Functional Group | Suffix | Example |
|---|---|---|
| Alkane | -ane | Propane |
| Alkene | -ene | Propene |
| Alkyne | -yne | Propyne |
| Alcohol | -ol | Propanol |
| Aldehyde | -al | Propanal |
| Ketone | -one | Propanone |
| Carboxylic Acid | -oic acid | Propanoic acid |
📝 Practice MCQs
Q1: The IUPAC suffix for an alcohol is:
a) -al b) -ol c) -one d) -oic acid
Show Answer
✅ b) -ol
Q2: A 5-carbon chain has the prefix:
a) But- b) Pent- c) Hex- d) Prop-
Show Answer
✅ b) Pent-
Q3: What is the correct IUPAC name for CH₃-CH₂-CHO?
a) Propanol b) Propanal c) Propanone d) Propanoic acid
Show Answer
✅ b) Propanal
Q4: When numbering a carbon chain, you should give the lowest locant to:
a) The last carbon b) The main functional group c) The middle carbon d) Any random carbon
Show Answer
✅ b) The main functional group
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