5 · Chemical Energetics
5.1 Exothermic and Endothermic Reactions
Exothermic reactions release energy to the surroundings (temperature increases) — e.g. combustion, neutralization.
Endothermic reactions absorb energy from the surroundings (temperature decreases) — e.g. thermal decomposition, dissolving certain salts.
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5.2 Energy Profile Diagrams and Bond Energy
In an exothermic reaction, products end up at a lower energy level than reactants (energy released). In an endothermic reaction, products end up at a higher energy level (energy absorbed).
Activation energy is the minimum energy needed for a reaction to start — the "hump" at the start of the energy profile, for both exo and endothermic reactions.
Overall energy change = energy absorbed breaking bonds in reactants − energy released forming bonds in products. Breaking bonds is always endothermic; forming bonds is always exothermic.
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